化学
生物正交化学
烷基
叠氮化物
半胱氨酸
点击化学
芳基
组合化学
有机化学
肽
联轴节(管道)
高分子化学
作者
Mei-Hua Shen,Yu-Jiao Wang,Yong Wang,Ying Zhou,Jie Gu,Xiao-Qian Liu,Jia Guo,Mingxing Ouyang,Linhong Deng,Hua-Dong Xu
摘要
α-Alkyl and α-aryl vinyl azides were found to be able to couple with cysteine-derived alkyl thiols chemoselectively under mild conditions, providing the corresponding β-ketosulfides with simultaneous extrusion of N 2 and ammonia.
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