化学
二乙胺
食腐动物
钯
催化作用
同种类的
水溶性
分子
原位
组合化学
有机化学
激进的
热力学
物理
作者
Sandrine Lemaire‐Audoire,Monique Savignac,Errol Blart,G. Pourcelot,J. P. Genêt,Jean-Marie Bernard
标识
DOI:10.1016/s0040-4039(00)78497-8
摘要
Allylcarboxy and Allyloxycarbonyl groups can be removed without affecting dimethylallylcarboxy and cinnamylcarboxy groups in the same molecule, using Pd(0) water soluble catalyst prepared in situ, with diethylamine as allyl scavenger. Homogeneous or biphasic media are suitable; the yields of deprotection are quantitative.
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