塔菲尔方程
过电位
电解质
化学工程
镍
材料科学
过渡金属
析氧
电催化剂
催化作用
分解水
三元运算
无机化学
化学
电极
冶金
电化学
有机化学
物理化学
光催化
工程类
计算机科学
程序设计语言
作者
Yong‐Ming Chai,Xiao Shang,Zi-Zhang Liu,Bin Dong,Gaorong Han,Wen-Kun Gao,Jing‐Qi Chi,Kai-Li Yan,Chenguang Liu
标识
DOI:10.1016/j.apsusc.2017.09.122
摘要
Mixed first-row transition metal-based sulfides with specific nanostructure hold the promising performances for oxygen evolution reaction (OER). Herein, based on the optimum Ni/Fe/Co ratio (8/1/1) in electrolyte for electrodeposition on nickel foam (NiFeCo/NF), ripple-like sNiFeCo/NF has been prepared as efficient electrode for water oxidation through solvothermal sulfurization. The unique ripple-like structures contain many pores and voids with many wrinkles and distortions, which may enlarge the surface area and expose more active sites, improving the contacting of catalyst/electrolyte interfaces and facilitate electron transfer. sNiFeCo/NF shows better OER activity than NiFeCo/NF, requiring overpotential of 180 mV to deliver 100 mA cm−2 and a low Tafel slope of 50.4 mV dec−1. In order to further overcome the poor stability of sNiFeCo/NF, Fe hydroxide film has been electrodeposited on the surface of sNiFeCo/NF (sNiFeCo-Fe/NF), which leads to enhanced stability at the sacrifice of partial activity loss of sNiFeCo/NF. The electrodeposited Fe is supposed to protect NiFeCo-based sulfides from severe corrosion in alkaline and ensure the OER activity in long-term water oxidation. It implies a balance between activity and durability of NiFeCo sulfides. This work may provide a facile routine to fabricate ternary Ni-Fe-Co sulfides as efficient electrocatalyst for water oxidation.
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