催化作用
沸石
产量(工程)
化学
碱金属
选择性
碱土金属
核化学
无机化学
有机化学
材料科学
冶金
作者
Atte Aho,Narendra Kumar,Kari Eränen,Robert Lassfolk,Päivi Mäki‐Arvela,Tapio Salmi,Markus Peurla,Ilari Angervo,Jukka Hietala,Dmitry Yu. Murzin
标识
DOI:10.1016/j.micromeso.2023.112483
摘要
Sn–Al-Beta zeolite was prepared through a hydrothermal method and further modified by alkali and alkaline earth (e.g. Sr and Ba) metals not practically altering the textural properties of the catalyst. The catalytic materials were tested in glucose transformation to methyl lactate in a batch reactor at 180 °C allowing to correlate catalytic activity and selectivity with the strength and type of acid sites. The results showed that by suppressing the Brønsted acidity of the modified catalyst with different promoters the yield of methyl lactate can be increased from ca. 20% to over 50%.
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