化学
硼酸化
有机硼化合物
电化学
组合化学
烷基
芳基
有机合成
有机催化
电解
有机化学
电子转移
纳米技术
催化作用
对映选择合成
物理化学
电极
材料科学
电解质
作者
Mohammad Moniruzzaman,Sadia Afrin,Md. Korban Ali
标识
DOI:10.1002/ajoc.202300090
摘要
Abstract Organoboron is a class of compounds widely used in organic synthesis, pharmaceuticals, material science, sensors, and so on. Therefore, the development of efficient and selective electrochemical methods to synthesize organoboron has attracted much interest as an emerging sustainable technique of organic synthesis. Here, we summarized research on electrochemical borylations, including the electrochemically driven borylation of arenes, alkanes, aryl, or alkyl halides, activated carboxylic acids etc., based on direct electrolysis and metal‐free organocatalysis. We focus on the reaction mechanisms involved in single‐electron transfer and other radical processes. We believe that this review will inspire electrochemists to discover more efficient transformations to expand this field of borylation.
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