High output flexible polyvinylidene fluoride based piezoelectric device incorporating cellulose nanofibers/BaTiO3@TiO2 piezoelectric core-shell structure

Flexible composite film has gained increasing attention in the fields of wearable devices and portable electronic products. In this work, a novel core-shell structure of cellulose nanofibers/BaTiO3@TiO2 (CNF/BTO@TiO2) was synthesized with the assistant of the biological macromolecule material of cellulose nanofibril (CNF), in which the CNF can improve the stability and dispersibility of BaTiO3 (BTO) in the aqueous phase and elevate the integrity of the core-shell structure. The agglomeration of nanoparticles and the structural defects of the composite film can be improved when the core-shell structure was uniformly dispersed in polyvinylidene fluoride (PVDF). Meanwhile, the core-shell structure can promote the polarization of the electric dipole and the formation of β phase in PVDF due to the generated interface spatial polarization between the shell of TiO2 and the core of BTO. When the content of the core-shell structure was 5 wt%, the β phase content reaches 61.89 %, and the piezoelectric coefficient of composite film reaches 84.29 pm/V. Thus the maximum output open-circuit voltage (VOC) and short-circuit current (ISC) of the piezoelectric composite film is as high as 13.10 V and 464.3 nA. In addition, its excellent pressure sensing capability allows for its application in various flexible electronic devices.