平面度测试
堆积
丝带
材料科学
聚合物
连接器
结晶学
形态学(生物学)
芯(光纤)
多孔性
纳米技术
化学物理
化学
有机化学
计算机科学
复合材料
操作系统
生物
遗传学
作者
Arjun Halder,Sharath Kandambeth,Bishnu P. Biswal,Gagandeep Kaur,Neha Chaki Roy,Matthew A. Addicoat,Jagadish K. Salunke,Subhrashis Banerjee,Kumar Vanka,Thomas Heine,Sandeep Verma,Rahul Banerjee
标识
DOI:10.1002/anie.201600087
摘要
Abstract Two new chemically stable triazine‐ and phenyl‐core‐based crystalline porous polymers (CPPs) have been synthesized using a single‐step template‐free solvothermal route. Unique morphological diversities were observed for these CPPs [2,3‐DhaTta (ribbon) and 2,3‐DhaTab (hollow sphere)] by simply altering the linker planarity. A detailed time‐dependent study established a significant correlation between the molecular level structures of building blocks with the morphology of CPPs. Moreover, a DFT study was done for calculating the interlayer stacking energy, which revealed that the extent of stacking efficiency is responsible for governing the morphological diversity in these CPPs.
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