二氧化碳
材料科学
合金
纳米颗粒
氮气
碳纤维
化学工程
二氧化氮
无机化学
纳米技术
化学
冶金
复合材料
有机化学
复合数
工程类
作者
Dongxing Tan,Jianling Zhang,Xiuyan Cheng,Xiuniang Tan,Jinbiao Shi,Bingxing Zhang,Buxing Han,Lirong Zheng,Jing Zhang
出处
期刊:Chemical Science
[The Royal Society of Chemistry]
日期:2019-01-01
卷期号:10 (16): 4491-4496
被引量:32
摘要
The electrocatalytic conversion of CO2 to CO using non-noble metal catalysts under mild conditions is of great importance. Achieving the combination of high activity, selectivity and current density by developing electrocatalysts with desirable compositions and structures is challenging. Here we prepared for the first time Cu x Ni y alloy nanoparticles embedded in a nitrogen-carbon network. Such an electrocatalyst not only well overcomes the disadvantages of single Cu and Ni catalysts but has a high CO2 adsorption capacity. Outstandingly, the catalyst can effectively convert CO2 into CO with a maximum faradaic efficiency of 94.5% and current density of 18.8 mA cm-2 at a low applied potential of -0.60 V (versus reversible hydrogen electrode, RHE). Moreover, the catalyst is very stable during long-term electrolysis owing to the stabilization of the nitrogen-carbon network.
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