光催化
兴奋剂
材料科学
带隙
纳米颗粒
可见光谱
吸收(声学)
纳米技术
分解
辐照
粒径
化学工程
光化学
催化作用
化学
光电子学
复合材料
有机化学
核物理学
工程类
物理
作者
Hui Miao,Gui‐Fang Huang,Jinhua Liu,Bing‐Xin Zhou,Anlian Pan,Wei‐Qing Huang,Guofang Huang
标识
DOI:10.1016/j.apsusc.2016.02.122
摘要
CeO2 nanoparticles are synthesized using a low-temperature solution combustion method and subsequent heat treatment in air. It is found that F-doping leads to smaller particle size and the formation of CeO2 nanocubes with higher percentage of reactive facets exposed. The band gap is estimated to be 3.16 eV and 2.88 eV, for pure CeO2 and fluorine doped CeO2 (F-doped CeO2) nanocubes, respectively. The synthesized F-doped CeO2 nanocubes exhibit much higher photocatalytic activities than commercial TiO2 and spherical CeO2 for the degradation of MB dye under UV and visible light irradiation. The apparent reaction rate constant k of MB decomposition over the optimized F-doped CeO2 nanocubes is 9.5 times higher than that of pure CeO2 and 2.2 times higher than that of commercial TiO2. The enhanced photocatalytic activity of F-doped CeO2 nanocubes originates from the fact that F-doping induces the small size, the highly reactive facets exposed, the intense absorption in the UV–vis range and the narrowing of the band gap. This research provides some new insights for the synthesis of the doping of the foreign atoms into photocatalyst with controlled morphology and enhanced photocatalytic activity.
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