Facile synthesis of acid-modified UiO-66 to enhance the removal of Cr(VI) from aqueous solutions

The adsorption behavior and mechanism of Cr(VI) on different acid-modified UiO-66s (Form-UiO-66 and Ac-UiO-66) were systematically investigated for the first time through a series of characterizations, and theoretical calculations of batch experiments. The characterization results demonstrate that acid-modified UiO-66 exhibited a larger specific surface area than did unmodified UiO-66. In addition, since the regulator (formic acid) of Form-UiO-66 was the stronger competition, the specific surface area of Form-UiO-66 (1138 m2 g-1) was larger than that of Ac-UiO-66 (915 m2 g-1). Under optimal experimental conditions, the maximum adsorption capacity of Cr(VI) was 243.9 mg g-1 on Form-UiO-66, and 151.52 mg g-1 on Ac-UiO-66, which was far higher than on the reported unmodified UiO-66 (36.4 mg g-1). The results of pH testing, zeta potential, and X-ray photoelectron spectroscopy analysis indicate that Cr(VI) ions were fixed to adsorbent surfaces via electrostatic adsorption. Acid-modified UiO-66 increased the surface active site via the increase in its specific surface area to enhance adsorption capacity of Cr(VI). These results indicated that both the surface charge and specific surface area of the adsorbent primarily determined the Cr(VI) adsorption capacity. Acid modified UiO-66 exhibited enhanced adsorption capacity, stability, and regeneration, compared to traditional adsorbents, and these results provide new insights into adsorption by MOFs.