量子点
荧光
量子产额
碳量子点
材料科学
光化学
石墨氮化碳
氮化碳
碳纤维
光电子学
化学
物理
光学
光催化
有机化学
催化作用
复合材料
复合数
作者
Xingchen He,Yixu Gu,Shichao Ai,Manman Xie,Qian Lu,Yiqing Wang,Jianquan Wang
标识
DOI:10.1016/j.apsusc.2018.08.091
摘要
A novel graphitic carbon nitride based quantum dots with controllable fluorescence emission wavelength were prepared by changing the primary framework of tri-s-triazine structure. Electron-rich heterocycle embedding of carbon nitride quantum dots with pyrimidine donors effectively increased the conjugation effect of electrons on triazine ring. More importantly, with the increase of asymmetrical heterocycle structures, the fluorescence emission peaks of the quantum dots gradually shifted from 425 nm to 575 nm, and the maximum fluorescence wavelength red shifted 700 nm. The maximum fluorescence quantum yield of this modified quantum dots is up to 22.39%. Those quantum dots have the advantages of improved water solubility and biocompatibility.
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