过电位
材料科学
钴
电催化剂
电池(电)
催化作用
纳米片
双功能
功率密度
电极
冶金
无机化学
纳米技术
化学工程
电化学
物理化学
有机化学
工程类
功率(物理)
化学
物理
量子力学
作者
Yang Liu,Lei Shi,Di Wang,Yanlong Lv,Dapeng Cao
出处
期刊:Nano Energy
[Elsevier]
日期:2018-08-01
卷期号:50: 691-698
被引量:292
标识
DOI:10.1016/j.nanoen.2018.06.023
摘要
To achieve wearable application, developing highly active and low cost non-precious metal bifunctional oxygen catalysts for foldable solid-state Zn-air battery is still a great challenge. Herein, we report a single-atom cobalt electrocatalyst with CoN4 moieties dispersed on nitrogen-doped graphitic nanosheet (marked as CoN4/NG) by a surfactant-assisted approach. The CoN4/NG catalyst exhibits excellent electrocatalytic activities with a half-wave potential of 0.87 V (versus RHE) for ORR and a low overpotential of 0.38 V at 10 mA cm−2 for OER. Moreover, the liquid Zn-air battery with the CoN4/NG catalyst as the air electrode displays a superior discharging and charging performance, larger power density, higher energy density and robust stability (without any decay after 100 h cycle test), compared to the 20% Pt/C + IrO2 counterpart. Importantly, the CoN4/NG-based flexible solid-state Zn-air battery also exhibits a high power density and a long-term stability of 30 cycles under flat and folded states, which means that the single-atom cobalt catalyst may be a promising candidate for practical applications in wearable flexible solid batteries.
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