Bioinspired, Recyclable, Stretchable Hydrogel with Boundary Ultralubrication

Although hydrogels exhibit excellent low frictional behavior, their friction coefficients cannot meet the requirements for biology, especially at low sliding velocities. Inspired by the natural lubrication mechanism from animals, plants, or even microorganisms, a nonionic surfactant, Tween 80, was introduced into a biofriendly poly(vinyl alcohol) (PVA) hydrogel to construct a composite hydrogel with ultralubrication. Such a combination endows PVA hydrogels with an ultralow coefficient of friction (10^-3 to 10^-4) under an extremely low sliding velocity (0.01 mm/s). Tween 80 micelles and aggregates, together with hydrophobic molds, induce rough surfaces and high carbon contents on the surface of the hydrogel, promoting excellent lubrication behavior of the composite hydrogel. In addition to the desirable lubrication, this environmentally friendly composite hydrogel also exhibited excellent flexibility at subzero temperatures, tensile properties, and good recyclability. Additionally, the method of introducing Tween 80 into hydrogels to reduce friction is also effective in chemically crosslinked double-network hydrogels.