阳极
石墨烯
材料科学
氧化物
电化学
锂(药物)
X射线光电子能谱
热液循环
锂离子电池
化学工程
电池(电)
电极
纳米技术
化学
冶金
量子力学
功率(物理)
物理化学
内分泌学
工程类
物理
医学
作者
Xiangang Zhai,Jianping Gao,Ruinan Xue,Xiaoyang Xu,Luyao Wang,Qiang Tian,Yu Liu
标识
DOI:10.1016/j.jcis.2018.02.012
摘要
Bi2MoO6/reduced graphene oxide (Bi2MoO6/rGO) composites were fabricated by a facile one-pot hydrothermal approach, in which Bi2MoO6 nanosheets and rGO were simultaneously obtained. The structure and composition of the as-synthesized Bi2MoO6 and Bi2MoO6/rGO materials were characterized via FT-IR, BET, TGA, XRD, TEM, SEM and XPS analyses, and the electrochemical performance of Bi2MoO6/rGO as an anode in a lithium-ion battery was investigated. Compared with pristine Bi2MoO6, the Bi2MoO6/rGO composites have higher capacities, better cycle stability and higher rates. For a current density of 100 mA g−1, the initial discharge capacities of the Bi2MoO6/rGO-20 and pristine Bi2MoO6 were 1049.6 mAh g−1 and 528.5 mAh g−1, respectively. After 100 cycles, the capacity retention for the Bi2MoO6/rGO-20 and pristine Bi2MoO6 were respectively 80.4% and 30.7% using the 2nd cycle capacities (895.8 and 402.4 mAh g−1) as references. The enhanced electrochemical performance can be ascribed to the synergistic effect of the Bi2MoO6 and rGO sheets, which dramatically improves the conductivities of the Bi2MoO6/rGO anodes. In addition, the rGO sheets also supply electron transfer routes for the anode and suppress volume changes of Bi2MoO6 nanosheets during the charge-discharge cycles.
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