Cascade Catalysis for the Hydrogenation of Carbon Dioxide to Methyl Formate Using a Molecular Ru–Phosphine Complex and the Metal–Organic Framework UiO-66 as Heterogeneous Acid

sponsorship: V.L., T.V., and D.E.D.V. acknowledge support from the Vlaio-Catalisti, through the Moonshot project RASCON, "reactive amine scrubbing for CO2 conversion" (RASCON-HBC.2020.2613). C.M. thanks VLAIO via the Flemish spearhead cluster Catalisti for financial support (Moonshot cluster SBO project PREFER, HBC.2020.2609 "Plastic refinery: no more waste"). (Vlaio-Catalisti, through the Moonshot project RASCON, "reactive amine scrubbing for CO2 conversion"|RASCON-HBC.2020.2613, VLAIO via the Flemish spearhead cluster Catalisti|HBC.2020.2609)