光子上转换
过氧化氢
检出限
荧光
纳米颗粒
纳米技术
发光
爆炸物
材料科学
化学
光电子学
光学
色谱法
物理
有机化学
作者
Yamin Feng,Da Lei,Baiyi Zu,Ji‐Guang Li,Yajuan Li,Xincun Dou
标识
DOI:10.1002/advs.202309182
摘要
Abstract The design and development of ultra‐accurate probe is of great significance to chemical sensing in complex practical scenarios. Here, a self‐accelerating naphthalimide‐based probe with fast response and high sensitivity toward hydrogen peroxide (H 2 O 2 ) is designed. By coupling with the specially selected upconversion nanoparticles (UCNPs), an ultra‐accurate colorimetric‐fluorescent‐upconversion luminescence (UCL) tri‐mode platform is constructed. Owing to the promoted reaction process, this platform demonstrates rapid response (< 1 s), an ultra‐low detection limit (4.34 nM), and superb anti‐interferent ability even in presence of > 21 types of oxidants, explosives, metallic salts, daily compounds, colorful or fluorescent substances. In addition, the effectiveness of this design is further verified by a sponge‐based sensing chip loaded with the UCNPs/probe in recognizing trace H 2 O 2 vapor from interferents with the three characteristic colors existing simultaneously. The proposed design of probe and tri‐mode visualization detection platform is expected to open up a brand‐new methodology for ultra‐accurate sensing.
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