Green Synthesis of Cerium-Based Metal–Organic Framework (Ce-UiO-66 MOF) for Wastewater Treatment

Green synthesis of metal-organic frameworks (MOFs) in aqueous solutions under ambient conditions with reduced production costs and environmental effects is an efficient technique to transfer lab-scale production to industrial large scale. Hence, this work proposes a green, low-cost, sustainable, rapid, and innovative synthetic strategy to produce cerium-based (Ce-UiO-66) MOFs under ambient conditions in the presence of water as a green solvent. This synthetic strategy exhibits great potential compared to conventional solvothermal synthetic techniques, and it does not need external activation energy and organic solvents, which can achieve the standards of green chemistry. Ce-UiO-66 MOF was synthesized successfully and utilized as a green adsorbent to efficiently eliminate anionic Congo Red (CR) dye from dye-containing wastewater. The experimental adsorption results were well matched to the pseudo-second-order kinetic and Langmuir isotherm models, in which the maximum CR adsorption capacity was measured to be about 285.71 mg/g. To evidence the applicability of Ce-UiO-66 MOFs in CR adsorption, the CR adsorption reaction was performed in the presence of interfering pollutants [e.g., salts (NaCl, KCl, and MgCl₂) and cationic organic dyes (Malachite Green (MG) and Methylene Blue (MB)], where the results prove the promising adsorption performances of Ce-UiO-66 MOFs toward CR dye. Interestingly, the synthesized adsorbent exhibited high structural stability during repeated adsorption-desorption cycles, where the surface area of MOFs decreased from 555 to 376 m²/g after three cycles, while its CR adsorption capacity decreased by only 10% compared to that of the fresh adsorbent. All these outstanding properties indicate that the Ce-UiO-66 MOFs will be an effective adsorbent for water and wastewater treatment applications.