单层
材料科学
氧化石墨
化学工程
图层(电子)
聚苯胺
氧化铟锡
氧化锡
纳米复合材料
氧化物
石墨
复合材料
高分子化学
纳米技术
聚合物
聚合
冶金
工程类
作者
Nina I. Kovtyukhova,Patricia J. Ollivier,Benjamin Martin,Thomas E. Mallouk,С. А. Чижик,E. Buzaneva,A. Gorchinskiy
摘要
Unilamellar colloids of graphite oxide (GO) were prepared from natural graphite and were grown as monolayer and multilayer thin films on cationic surfaces by electrostatic self-assembly. The multilayer films were grown by alternate adsorption of anionic GO sheets and cationic poly(allylamine hydrochloride) (PAH). The monolayer films consisted of 11−14 Å thick GO sheets, with lateral dimensions between 150 nm and 9 μm. Silicon substrates primed with amine monolayers gave partial GO monolayers, but surfaces primed with Al13O4(OH)24(H2O)127+ ions gave densely tiled films that covered approximately 90% of the surface. When alkaline GO colloids were used, the monolayer assembly process selected the largest sheets (from 900 nm to 9 μm) from the suspension. In this case, many of the flexible sheets appeared folded in AFM images. Multilayer (GO/PAH)n films were invariably thicker than expected from the individual thicknesses of the sheets and the polymer monolayers, and this behavior is also attributed to folding of the sheets. Multilayer (GO/PAH)n and (GO/polyaniline)n films grown between indium−tin oxide and Pt electrodes show diodelike behavior, and higher currents are observed with the conductive polyaniline-containing films. The resisitivity of these films is decreased, as expected, by partial reduction of GO to carbon.
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