Photocatalytic CO2 Reduction to Multi‐Carbon Products

Abstract Photocatalytic CO 2 reduction represents a sustainable pathway for mitigating carbon emissions and producing renewable chemicals by utilizing solar energy. While extensive research has been dedicated to single‐carbon (C 1 ) products, the selective formation of multi‐carbon (C 2+ ) compounds, such as ethylene, ethane, ethanol and acetic acid, has garnered increasing attention due to their higher energy density and broader industrial relevance. However, achieving efficient C─C coupling under mild photocatalytic conditions remains a formidable challenge, hindered by complex reaction pathways, sluggish kinetics and competitive side reactions. In this review, recent advances in photocatalytic CO 2 reduction to C 2+ products was systematically summarized, focusing on fundamental reaction mechanisms, rational photocatalyst design strategies, including atomically dispersed active sites, cocatalyst loading, defect engineering, and localized surface plasmon resonance (LSPR). By bridging mechanistic understanding with materials innovation, this review provides a comprehensive framework for guiding the development of next‐generation photocatalytic systems for efficient and selective CO 2 ‐to‐C 2+ conversion, contributing to sustainable carbon utilization and circular chemical economy.