薄泥浆
原电池
腐蚀
材料科学
电偶腐蚀
阴极保护
预应力混凝土
电流密度
碳化作用
电流(流体)
复合材料
电偶阳极
岩土工程
冶金
地质学
电化学
工程类
电极
化学
电气工程
量子力学
物理化学
物理
作者
Karthikeyan Manickam,Radhakrishna G. Pillai
出处
期刊:Corrosion
[NACE International]
日期:2023-11-30
卷期号:80 (2): 130-141
被引量:3
摘要
Grouted, post-tensioned (PTD) concrete systems are widely used to construct bridges, typically with an anticipated corrosion-free service life of 100+ y. However, the usage of inadequate grout materials and grouting practices in PTD concrete systems have caused unwanted air voids in ducts, leading to strand/grout/air interface, carbonation of exposed grout layer, and localized corrosion of strands (say, within about 10 y to 20 y). Re-grouting of voids as a tendon repair strategy has led to accelerated galvanic corrosion of the portion of strands at the interface between the carbonated base grout and repair grout with different chemistry, raising concerns and reluctance in re-grouting of voids in tendons. This work focused on understanding and quantifying the galvanic corrosion at the interface of carbonated base grout and repair grout in a re-grouted tendon. The theoretical analysis based on mixed potential theory estimated a galvanic current density of approximately 2 µA/cm2 and showed that the galvanic coupling can increase the corrosion current density of the prestressing steel in the base grout by about two-fold. The study on prestressed steel in simulated solutions estimated a galvanic current density of approximately 20 µA/cm2. Then, the study on prestressing steel in grouts and the analytical simulation estimated galvanic current densities around 1.5 µA/cm2 to 2 µA/cm2 at 95% external relative humidity (ERH) and 25°C. A model relating the galvanic current density in grouted systems as a function of ERH was developed, which showed an exponential increase in the galvanic corrosion with an increase in ERH. Also, a case study showed that if the tendon anchorage region experiences 95% ERH for about 20 y, sufficient strand corrosion could happen, and structural behavior can change from ductile to brittle nature, which could be a serious concern for structures in the coastal zone.
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