Simultaneous Cr(VI) reduction and Cr(III) sequestration in a wide pH range by using magnetic chitosan-based biopolymer

The simultaneous reduction of Cr(VI) and sequestration of the resulting Cr(III) in one process is highly desirable as a cost-effective and environmental-friendly approach for the decontamination of Cr(VI)-polluted wastewater. However, most of the existing adsorptive materials are only effective in low pH environments (pH = 1–3), severely restricting the adsorption efficiency and cost effectiveness. Herein, we proposed a chitosan-based magnetic porous microsphere (PPy@PMCS) for simultaneous Cr(VI) reduction and Cr(III) sequestration in a wide pH range. Benefiting from its abundant interaction sites, Cr(VI) was effectively adsorbed on the surface and then immediately reduced to Cr(III) with much lower toxicity. Most importantly, the resulting Cr(III) was in-situ sequestrated by the complexation of chitosan matrix. As a result, PPy@PMCS exhibited a maximum Cr(VI) adsorption capacity of 330.42 mg/g at pH 2.0 and an adsorption capacity of 167.82 mg/g even at near neutral pH (6.0), which is superior to most reported adsorbents. Furthermore, the exhausted PPy@PMCS can be rapidly separated from solutions under an external magnetic field and facilely regenerated. The proposed novel biopolymer-based material shows great application potentials in wastewater treatment.