Elucidating Surface Plasmon Damping and Fano Resonance Induced by Epitaxial Growth of Palladium on Single Gold Nanorods

Plasmon damping and Fano resonance induced in the growth of palladium (Pd) on gold nanorods (AuNRs) have been poorly understood. Herein, we investigated the optical properties and morphologies of single AuNRs@Pd (core@shell) synthesized using epitaxial Pd growth at different Pd concentrations. The localized surface plasmon resonance (LSPR) spectra of single AuNRs@Pd showed characteristic subradiant and superradiant peaks as well as Fano resonance as a spectral dip, which was highly influenced by the Pd shell thickness. The occurrence of the Fano resonance during the Pd growth was further verified by in situ real-time observation experiments. We then elucidated time-dependent, real-time variations in LSPR peak wavelength, metal-induced surface damping, and Fano resonance mode of single AuNRs@Pd during Pd shell formation in three successive phases: Pd reduction, nucleation, and growth. Therefore, this study provides new insights into metal interface damping, the Fano resonance, and optical tunability by engineering the Fano resonance energy and Pd shell thickness.