Single‐Atom Co‐Ultrafine RuOx Clusters Codecorated TiO2 Nanosheets Promote Photocatalytic Hydrogen Evolution: Modulating Charge Migration, H+ Adsorption, and H2 Desorption of Active Sites

Abstract Ru as a cocatalyst has attracted wide attention as a substitute for Pt precious metal. However, the strong interaction between Ru and H atoms reduces the efficiency of hydrogen (H 2 ) desorption and slows the overall hydrogen evolution reaction (HER) efficiency. How to further improve the efficiency of Ru‐based cocatalyst is challenging. Herein, single‐atom Co‐ultrafine RuO x clusters codecorated TiO 2 nanosheets for photocatalytic HER are synthesized using a simple hydrothermal–calcination method. Experiments and theoretical calculations demonstrate that Co atoms can serve as a specific electronic medium, promoting electron enrichment at RuO x , thereby enhancing the adsorption of H + . Moreover, the electronic state of the interaction between adjacent Co atoms and RuO x is conducive to the desorption of H 2 . As a result, the proposed photocatalyst system gives a classy photocatalytic HER performance. The hydrogen production rate at stationary point reaches up to 20.20 mmol g −1 h −1 , and the apparent quantum yield at 365 nm is 86.5%. It is worth noting that the hydrogen production rate in seawater is as high as 9.83 mmol g −1 h −1 . This work offers precise guidance to design catalysts for efficient photocatalytic H 2 production from the in‐depth understanding of the electronic coupling effect of coupling active sites.