芳烯
膜
乙醚
砜
高分子化学
酮
热稳定性
电导率
肿胀 的
质子交换膜燃料电池
化学
质子核磁共振
金属有机骨架
材料科学
核化学
芳基
烷基
物理化学
有机化学
生物化学
吸附
复合材料
作者
L. Meng,Mengchi Ju,Jingmei Xu,Xuan Chen,Pengyun Zhao,Jinxuan Lei,Li Tian,F.R. Chen,Zhongliang Hu,Zhe Wang
标识
DOI:10.1016/j.ijhydene.2023.07.148
摘要
In this paper, sulfonated poly(arylene ether ketone sulfone)s containing fluorenyl groups (F-SPAEKS) were synthesized. MIL-101-NH2 was prepared by hydrothermal reaction. The carboxyl group was modified to MIL-101-NH2 by amidation reaction, then difunctional MIL-101-NH2 was designed (MIL-101-NH2-COOH). The fillers of MIL-101-NH2 and difunctional MIL-101-NH2-COOH were added into F-SPAEKS matrix to prepare the hybridized membranes, respectively. The structures and morphologies of MIL-101-NH2, MIL-101-NH2-COOH and hybridized membranes were characterized by SEM, FT-IR, 1H NMR, XPS and XRD. Among these prepared hybridized membranes, FSMNC-4 (the weight percentage of MIL-101-NH2-COOH was 4%) had the highest proton conductivity (159.90 mS cm−1 at 80 °C). The proton conductivity of FSMNC-4 was 1.79 times higher than that of pure F-SPAEKS (89.30 mS cm−1 at 80 °C) and 1.25 times higher than that of FSMN-4 (the weight percentage of MIL-101-NH2 was 4%) (127.55 mS cm−1 at 80 °C), respectively. Meanwhile, the increase of hydrophilic groups also resulted in the highest water absorption of FSMNC-4 (21.57% at 80 °C). The ionic cross-linked networks reduced the swelling ratio of the hybridized membranes. The swelling ratio of all hybridized membranes was lower than 10%. FSMNC-4 also had good thermal and oxidative stability. The open circuit voltage (OCV) and maximum power density of FSMNC-4 were 0.994 V and 466 mW/cm2, respectively. The above results indicated that FSMNC-4 had a promising potential to be applied in PEMFCs.
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