Extraction of the cellulose nanocrystals via ammonium persulfate oxidation of beaten cellulose fibers

The effect of beating starting pulp was investigated on the oxidation efficiency of ammonium persulfate (APS), the yield, and the properties of the CNCs. The beaten pulp and the subsequent CNCs were characterized, respectively, by different techniques. The CNCs were classified as CNC1 and CNC2, dependent on ultrasonication. It showed that the beating exposed more free OH groups in the pulp and enhanced the yield and surface charges of CNCs. Compared to the CNC2, the CNC1 had a higher surface charge, higher crystallinity, higher thermal stability, shorter length, smaller length distribution, and slightly larger width. The CNC1 and CNC2 had similar rheological properties. For the beaten pulp with a beating degree of 25°SR, the yields of the CNC1 and the total CNCs reached the maximum, 42.65 and 34.11 %, respectively. The surface charges of the CNC1 and the CNC2 also reached the maximum, -44.5 and - 33.6 mV, respectively. Their crystallinity indexes were 80.07 and 75.42 %, respectively. The lengths of the CNC1 and the CNC2 were 157.31 ± 30.61 and 214.92 ± 65.52 nm, and their widths were 10.13 ± 2.74 and 9.43 ± 2.99 nm, respectively. Therefore, proper beating enhanced the APS oxidation efficiency and influenced the CNCs properties.