CNT‐Supported RuNi Composites Enable High Round‐Trip Efficiency in Regenerative Fuel Cells

Abstract Regenerative fuel cells hold significant potential for efficient, large‐scale energy storage by reversibly converting electrical energy into hydrogen and vice versa, making them essential for leveraging intermittent renewable energy sources. However, their practical implementation is hindered by the unsatisfactory efficiency. Addressing this challenge requires the development of cost‐effective electrocatalysts. In this study, a carbon nanotube (CNT)‐supported RuNi composite with low Ru loading is developed as an efficient and stable catalyst for alkaline hydrogen and oxygen electrocatalysis, including hydrogen evolution, oxygen evolution, hydrogen oxidation, and oxygen reduction reaction. Furthermore, a regenerative fuel cell using this catalyst composite is assembled and evaluated under practical relevant conditions. As anticipated, the system exhibits outstanding performance in both the electrolyzer and fuel cell modes. Specifically, it achieves a low cell voltage of 1.64 V to achieve a current density of 1 A cm − 2 for the electrolyzer mode and delivers a high output voltage of 0.52 V at the same current density in fuel cell mode, resulting in a round‐trip efficiency (RTE) of 31.6% without further optimization. The multifunctionality, high activity, and impressive RTE resulted by using the RuNi catalyst composites underscore its potential as a single catalyst for regenerative fuel cells.