Nonconventional Silicon‐Hybrid Luminophores of Hyperbranched Polymer: Fluorescence Regulation and Applications

Hyperbranched polysiloxanes are a class of nonconventional polymers with unique structural features and excellent physicochemical properties, which have attracted great attention in the field of luminescent materials. This review summarizes the recent progress in the study of luminescence mechanisms and optical properties of various hyperbranched polymers containing Si‐O‐C segments with Si as branching points, including hyperbranched polysiloxanes, hyperbranched polyborosiloxanes, and hyperbranched polysilphosphates. Through molecular design and structural regulation, researchers have successfully achieved multi‐color fluorescence and room‐temperature phosphorescence emission ranging from blue to red in these polymers, with quantum yields reaching up to 54.1% and fluorescence lifetimes up to 9.73 μs. The AIE properties and excellent biocompatibility of these polymers provide new materials and strategies for applications in bioimaging, controlled drug release, information security encryption, and ion detection. Moreover, the opportunities and challenges for further development are briefly discussed.