Ultramicroporous Crosslinked Polyxanthene-Poly(biphenyl piperidinium)-based Anion Exchange Membranes for Water Electrolyzers Operating under Highly Alkaline Conditions

Anion exchange membrane water electrolyzers (AEMWEs) suffer from low efficiencies and durability, due to the unavailability of appropriate anion exchange membranes (AEM). Herein, a rigid ladder-like polyxanthene crosslinker was developed for the preparation of ultramicroporous crosslinked polyxanthene-poly(biphenyl piperidinium)-based AEMs. Due to the synergetic effects of their ultramicroporous structure and microphase-separation morphology, the crosslinked membranes showed high OH