Scalable-Manufactured Anticorrosion and Wear-Resistant Superhydrophobic Surfaces

砂纸 含氟聚合物 腐蚀 磨损(机械) 材料科学 耐化学性 生物污染 摩擦腐蚀 纳米技术 超疏水涂料 耐久性 接触角 复合材料 聚合物 电化学 膜 化学 电极 物理化学 生物 遗传学
作者
Wei Ma,Zhen Yang,Muhammad Bilal Asif,Yinglun Zhang,Weihong Li,Jinglei Yang,Shuhuai Yao
出处
期刊: [American Chemical Society]
卷期号:1 (1): 519-529 被引量:21
标识
DOI:10.1021/acsaenm.2c00122
摘要

Superhydrophobic surfaces have attracted considerable attention because of their unique characteristics for widespread applications such as self-cleaning, de-icing, anti-fouling and drag reduction. However, previous research has failed to attain the required mechanical and chemical robustness simultaneously on a superhydrophobic surface, which has significantly limited its application in complex and practical scenarios. In this work, we have designed and fabricated a mechanically and chemically robust superhydrophobic surface with a high water contact angle of 160.1° and a low sliding angle of 2.7°. We achieved this through laser ablation to obtain micro-structured stainless steel frames, followed by filling nano-scale fluoropolymer internal coatings. Here the stainless steel protective frames have significantly enhanced mechanical durability of the surface and the fluoropolymer coatings have improved chemical corrosion resistance due to intrinsic chemical inertness. Thus, the synergetic effect of mechanical protective structures and chemical inertness allows the superhydrophobic surface to maintain superhydrophobicity even after sandpaper abrasion and chemical immersion. In addition, our superhydrophobic surface has exhibited potential for outdoor applications after performing well for 30-day tests under UV and thermal exposure, salt spray, and seawater immersion. We envision that such superhydrophobic surfaces with their superior mechanical robustness, chemical corrosion resistance, and scalable manufacturability are capable of expanding their operational lifespan in real-world applications.
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