共价有机骨架
二氧化碳
共价键
电催化剂
氧化还原
化学
二氧化碳电化学还原
组合化学
分子
化学工程
无机化学
电化学
有机化学
催化作用
工程类
一氧化碳
物理化学
电极
作者
Minghao Liu,Shuai Yang,Yubin Fu,Xiubei Yang,Xuewen Li,Jun He,Qing Xu,Gaofeng Zeng
标识
DOI:10.1016/j.cej.2024.150812
摘要
Covalent organic frameworks (COFs) constructed with metallocyclophane units and organic linkers have found application as electrocatalytic systems. Nevertheless, the majority of linkers within COFs necessitate intricate design and synthesis. Conversely, the potential utilization of natural building blocks in COF construction remains largely unexplored. In this study, we constructed a natural COF (CoPc-EA-COF) by employing a natural phenolic molecule (ellagic acid (EA)) as the linker and Co-hexadecafluorophthalocyanine (CoPc) as blocks. This framework serves as an electrocatalyst for both the oxygen reduction reaction (ORR) and carbon dioxide reduction reaction (CO2RR). The incorporation of EA units imparts the CoPc-EA-COF with elevated electronic conductivity, enhanced CO2 binding affinity, and superior reductive capacity compared to the controlled COF lacking EA units. The CoPc-EA-COF demonstrated enhanced performance in the ORR, as evidenced by a half-wave potential of 0.80 V. Moreover, it showcased elevated activity and selectivity in the CO2RR, achieving a maximum CO faradic efficiency of 97.32 % at − 0.8 V, along with turnover frequency (TOF) values reaching 2092 h−1. Theoretical calculations revealed that the presence of EA units facilitated the generation of OOH* and COOH* species, which are pivotal in the rate-determining stages of both ORR and CO2RR processes. The contribution of EA units significantly bolstered the overall catalytic activity.
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