Graphene‐Encapsulated Bifunctional Catalysts with High Activity and Durability for Zn–Air Battery

Abstract Carbon‐based electrocatalysts with both high activity and high stability are desirable for use in Zn–air batteries. However, the carbon corrosion reaction (CCR) is a critical obstacle in rechargeable Zn–air batteries. In this study, a cost‐effective carbon‐based novel material is reported with a high catalytic effect and good durability for the oxygen reduction reaction (ORR) and oxygen evolution reaction (OER), prepared via a simple graphitization process. In situ growth of graphene is utilized in a 3D‐metal‐coordinated hydrogel by introducing a catalytic lattice of transition metal alloys. Due to the direct growth of few‐layer graphene on the metal alloy decorated 3d‐carbon network, greatly reduced CCR is observed in a repetitive OER test. As a result, an efficient bifunctional electrocatalytic performance is achieved with a low Δ E value of 0.63 V and good electrochemical durability for 83 h at a current density of 10 mA cm −2 in an alkaline media. Moreover, graphene‐encapsulated transition metal alloys on the nitrogen‐doped carbon supporter exhibit an excellent catalytic effect and good durability in a Zn–air battery system. This study suggests a straightforward way to overcome the CCR of carbon‐based materials for an electrochemical catalyst with wide application in energy conversion and energy storage devices.