Carbon‐Based Electrocatalysts for Efficient Hydrogen Peroxide Production

Abstract Hydrogen peroxide (H 2 O 2 ) is an environment‐friendly and efficient oxidant with a wide range of applications in different industries. Recently, the production of hydrogen peroxide through direct electrosynthesis has attracted widespread research attention, and has emerged as the most promising method to replace the traditional energy‐intensive multi‐step anthraquinone process. In ongoing efforts to achieve highly efficient large‐scale electrosynthesis of H 2 O 2 , carbon‐based materials have been developed as 2e − oxygen reduction reaction catalysts, with the benefits of low cost, abundant availability, and optimal performance. This review comprehensively introduces the strategies for optimizing carbon‐based materials toward H 2 O 2 production, and the latest advances in carbon‐based hybrid catalysts. The active sites of the carbon‐based materials and the influence of coordination heteroatom doping on the selectivity of H 2 O 2 are extensively analyzed. In particular, the appropriate design of functional groups and understanding the effect of the electrolyte pH are expected to further improve the selective efficiency of producing H 2 O 2 via the oxygen reduction reaction. Methods for improving catalytic activity by interface engineering and reaction kinetics are summarized. Finally, the challenges carbon‐based catalysts face before they can be employed for commercial‐scale H 2 O 2 production are identified, and prospects for designing novel electrochemical reactors are proposed.