氯化胆碱
深共晶溶剂
化学
尿素
溶剂
折射率
氢键
粘度
电导率
摩尔电导率
摩尔体积
共晶体系
无机化学
分析化学(期刊)
热力学
有机化学
色谱法
物理化学
分子
材料科学
元素分析
光电子学
物理
合金
作者
Chunlu Li,Niannian Wang,Yuanlin Yao,Zhifang Cui,Jun Gao,Dexin Feng
标识
DOI:10.1080/00319104.2021.1916930
摘要
To convert carbohydrates into platform compounds, the deep eutectic solvent (DES) based on choline chloride and urea (molar ratio 1:2) was adopted as a green solvent. The physical properties of density, dynamic viscosity, conductivity and refractive index were determined for the mixture of D-glucose and DES including neat reline at a temperature from 293.15 K to 363.15 K at 101.3 kPa. The measured data of density, dynamic viscosity, conductivity and refractive index were correlated, respectively. Meanwhile, the molecular volume, standard molar entropy, lattice energy and free volume were calculated. The spectra of FTIR indicates that the hydrogen bond was changed in the mixture with increasing the content of D-glucose.
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