Spin-glass-like freezing in spin-chain compounds Ca3Co2−xMnxO6: Effect of disorder

We have illustrated the presence of spin-glass-like freezing in the Mn-doped spin-chain compounds Ca3Co2−xMnxO6, which was not reported previously. With increasing Mn composition, the magnetic relaxation due to spin freezing is gradually suppressed. Interestingly, the magnetization in the intermediate Mn compositions relaxes more slowly (characteristic time is significantly enhanced) than those in x = 0.0 and 1.0. This could be understood within the framework of disorder with randomness or imperfections, which plays an important role in the formation of spin-glass-like feature in intermediate Mn compositions, quite different from the cases in x = 0.0 with strong spin frustration and in x ∼ 1.0 with perfect Co/Mn ionic order.