电催化剂
催化作用
材料科学
电化学
氢
拓扑缺陷
拓扑(电路)
纳米技术
碳纤维
化学
电极
物理化学
物理
有机化学
电气工程
复合数
工程类
复合材料
量子力学
作者
Xin Wang,Yi Jia,Xin Mao,Longzhou Zhang,Daobin Liu,Song Li,Xuecheng Yan,Jun Chen,Dongjiang Yang,Jizhi Zhou,Kang Wang,Aijun Du,Xiangdong Yao
出处
期刊:Chem
[Elsevier]
日期:2020-08-01
卷期号:6 (8): 2009-2023
被引量:117
标识
DOI:10.1016/j.chempr.2020.05.010
摘要
Metal-free carbon catalysts, especially with rich topological defects, have exhibited extraordinary performance in various electrochemical reactions. To fundamentally understand the relation of activity with specific defect, control of defect type in carbon is indispensable and unfortunately still remains a great challenge to date. Here, we developed a general edge-engineering method to produce a class of definitive defect configurations converted from corresponding specific nitrogen (N) doping sites. Theoretical simulations provide the fundamental capability and the design principles. Experimentally, structural characterizations clearly elucidate the specific one-to-one conversion of confirmative N configuration to carbon defect; e.g., graphitic-N to divacancy (C585), pyridinic-N to separate pentagon (S-C5), and pyrrolic-N to adjacent pentagons (A-C5), respectively. For electrocatalysis, A-C5 defects show the highest intrinsic activity in oxygen reduction reaction, whereas C585 defects perform the best in hydrogen evolution reaction. This work provides the main guidance in design of carbon-based catalysts via control of target defect synthesis.
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