双功能
取代基
化学
配体(生物化学)
过电位
电化学
配位聚合物
结晶学
拓扑(电路)
咪唑
立体化学
晶体结构
催化作用
物理化学
有机化学
电极
受体
组合数学
生物化学
数学
作者
Rajib Moi,Karabi Nath,Kumar Biradha
标识
DOI:10.1002/asia.201901123
摘要
Three CdII coordination polymers (CPs) were synthesized with a tripodal ligand N,N',N' '-tris(4-pyridinylmethyl)-1,3,5-benzenetricarboxamide in combination with three different substituted isophthalic acids with general formulas {[Cd2 (L)(NIP)2 (H2 O)2 ].4H2 O}n , (CP-1), {[Cd2 (L)(AIP)2 (H2 O)2 ].4H2 O}n , (CP-2) and {[Cd(L)(BIP) (H2 O)].4H2 O}n , (CP-3). The substituent groups on the co-ligand had profound effect on the network topologies of the corresponding CPs as well as their properties. Out of the three, CP-1 and 2 were found to form 3D networks whereas CP-3 was a 1D linear chain with uncoordinated pyridyl sites. Due to its structural features CP-3 was found to show interesting properties. The 1D CP containing uncoordinated pyridyl site exhibited an excellent ability for doping with CoII which in turn acts as an efficient water oxidation electrocatalyst with required overpotential of 380 mV for an anodic current density of 1 mA cm-2 . The CP also exhibited luminescence-based detection of nitroaromatics (LOD: 0.003 mm) without any significant interference in presence of other organic compounds.
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