Carbonation characteristics of CaO and calcined dolomite and calcination characteristics of dolomite were investigated in this paper.The results show that CaO can effectively absorb CO2 under the atmosphere of 20%vol CO2 in the temperature range of 550 ~700 ℃;CaCO3 began to decompose at 800°C,reaching the greatest decomposition rate at 870 ℃;Decomposition of dolomite takes place in two steps.In nitrogen atmosphere,temperature range of the two steps partially overlaps;In CO2 atmosphere,CaCO3 decomposes at higher temperature,making the two step reactions separated clearly.