Porous Metal–Organic Framework Liquids for Enhanced CO2 Adsorption and Catalytic Conversion

Abstract The unique applications of porous metal–organic framework (MOF) liquids with permanent porosity and fluidity have attracted significant attention. However, fabrication of porous MOF liquids remains challenging because of the easy intermolecular self‐filling of the cavity or the rapid settlement of porous hosts in hindered solvents that cannot enter their pores. Herein, we report a facile strategy for the fabrication of a MOF liquid (Im‐UiO‐PL) by surface ionization of an imidazolium‐functionalized framework with a sterically hindered poly(ethylene glycol) sulfonate (PEGS) canopy. The Im‐UiO‐PL obtained in this way has a CO 2 adsorption approximately 14 times larger than that of pure PEGS. Distinct from a porous MOF solid counterpart, the stored CO 2 in Im‐UiO‐PL can be slowly released and efficiently utilized to synthesize cyclic carbonates in the atmosphere. This is the first example of the use of a porous MOF liquid as a CO 2 storage material for catalysis. It offers a new method for the fabrication of unique porous liquid MOFs with functional behaviors in various fields of gas adsorption and catalysis.