The formation of iron oxide hydroxide in a ferrous sulfate was studied in different contents of iron in the solution at a temperature range of 90 to under 13 atmospheres. The Mohr's salt thus formed was hydrolyzed under 1 to 3 atmospheres, in 14 to 72 g/l of iron content in the solution pH 3 or 6 for two hours at 90 to . The results obtained was as follows; 1) In Mohr's salt solution, as the iron content was increased, with decreasing the concentration of hydrogen ion, the yield of iron oxide hydroxide was gradually increased. 2) When iron content in Mohr's salt solution was 42.81 g/l, 91.5% of iron was recovered in the form of -goethite similar to yellow grade of natural goethite. 3) When -goethite obtained was calcined of , it was turned into -ferric oxide with a redish brown colour.