Bioinspired Binary-Site Catalysts for Novel Urea-Assisted Zn-air Battery: A Transfer Station between Renewable Energy and Hydrogen

The slow reaction kinetics of oxygen electrode is the bottleneck restricting the development of rechargeable Zn-air batteries (ZABs). In order to further improve the energy conversion efficiency of ZABs, a novel urea-assisted ZAB system was proposed by replacing oxygen evolution reaction (OER) with urea oxidation reaction (UOR) with lower theoretical thermodynamic potential. Inspired by nature's ingenious structure-function, a "leaf-branch" CoNi@NCNTs-LDH/CC binary-site electrocatalyst was designed for the above system, where spatially separated branches and leaves serve as the main active sites for ORR and UOR, respectively. A build-in electric field from CoNi-LDH to CoNi@NCNTs is formed at the interface of the composite, which plays a command effect, effectively triggering the accumulation of O2 and urea reactants around the CoNi and LDH sites, respectively, and thus improving the efficiency of both ORR and UOR reactions. Based on that, a conceptual urea-assisted rechargeable ZAB is demonstrated to have significantly decreased charging voltage, higher energy conversion efficiency (74.6%) compared with the conventional ZAB, as well as high urea elimination rates. Considering the urea-assisted ZAB with high energy conversion efficiency and wastewater treatment versatility as an energy transfer station applied in a high value-added agricultural system, uninterrupted hydrogen production and wastewater treatment of agricultural wastewater can be simultaneously achieved using sustainable energy sources.