ZIF-67 and Cobalt-based@heteroatom–doped carbon nanomaterials for hydrogen production and dyes removal via adsorption and catalytic degradation

Metal-organic frameworks (MOFs) are promising catalysts for producing clean energy and environmental-based applications. This paper reported one-pot encapsulation of guest molecules, e.g., thiourea (TU) and D-Glucose-6-phosphate disodium salt dihydrate (G6P-Na 2 ), into zeolitic imidazolate frameworks (ZIF-67). The organic guest molecules offered the synthesis of carbon nanomaterials (S@ZIF-67 and P@ZIF-67) and cobalt-based materials (e.g., Co 3 O 4 , CoP, and CoS), embedded heteroatoms (P, N, and S) via carbonization. The materials were tested for hydrogen generation via sodium borohydride (NaBH 4 ) hydrolysis. ZIF-67, S@ZIF-67, and P@ZIF-67 displayed maximum hydrogen generation rates (HGR max ) of 27273, 24000, and 60000 mL H2 g cat −1 min −1 , respectively, using 20 mg of the catalyst and 0.2 wt.% of NaBH 4 at 60 °C. The materials were also investigated as potential catalysts for the adsorption and catalytic degradation of water pollutants such as organic dyes, e.g., methyl orange (MO) and Congo red (CR), with degradation efficiency of 100% and 99% in a short time (30-60 min). • Report environmentally friendly synthesis method for metal-organic frameworks (MOFs) • Synthesis of cobalt-based nanomaterials using MOFs as precursors • Record high hydrogen production via NaBH 4 hydrolysis • Successfulul degrade organic pollutants via in situ generated hydrogen