等离子体子
表面等离子体子
表面等离子共振
催化作用
局域表面等离子体子
分解水
表面等离子体激元
材料科学
联轴节(管道)
电化学
波长
氢
光催化
化学
光化学
化学物理
化学工程
纳米颗粒
光电子学
纳米技术
电极
复合材料
物理化学
有机化学
工程类
生物化学
作者
Anna Zabelina,Elena Miliutina,D. Zabelin,Vasilii Burtsev,Vladislav Buravets,Roman Elashnikov,Viktorie Neubertova,Martin Šťastný,Daniela Popelková,J. Lančok,Sergii Chertopalov,Martin Paidar,Andrii Trelin,Alena Michalcová,Václav Švorčík,Oleksiy Lyutakov
标识
DOI:10.1016/j.cej.2022.140441
摘要
Hybridization of catalytic and plasmon active materials provides an elegant way for efficiently improving of photo-electrochemical (PEC) water splitting. In this work, we propose the utilization of the plasmon coupling between surface plasmon polariton (SPP) and localized surface plasmon (LSP) for gigantic light concentration and triggering of the catalytic activity of titanium diboride (TiB2) flakes. The enhancement of TiB2 flakes' catalytic activity as a result of coupled plasmon triggering was investigated in PEC, including hydrogen and oxygen evolution half-reactions (HER and OER) performed in alkaline and acidic conditions. Additional studies performed at various light wavelengths and the time-dependent response of the structure show that the catalytic activity is triggered through the excitation of electron-hole pairs in TiB2 and their subsequent separation/acceleration in strong coupled plasmons field. In general, our work provides one of the first attempts how to realize a symmetric and less pH-sensitive catalyst for PEC water splitting.
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