石墨烯
材料科学
石油化工
弹性体
氧化物
异氰酸酯
复合材料
热稳定性
表面改性
化学工程
纳米技术
聚氨酯
有机化学
化学
冶金
工程类
作者
Ernesto Águila-Toledo,Santiago Maldonado-Magnere,Mehrdad Yazdani‐Pedram,Allan Bascuñan‐Heredia,Mohamed Dahrouch,F. Molina,Marianella Hernández Santana,Raquel Verdejo,Miguel A. López‐Manchado,Héctor Aguilar‐Bolados
标识
DOI:10.1021/acsapm.3c00949
摘要
In this work, we develop fluorosilicone elastomer (FSE) compounds with advanced properties by incorporating graphene oxides functionalized with vinyltrimethoxysilane (GO-V) and allyl isocyanate (GO-A). The morphology and structure of the graphene oxides were characterized confirming the successful functionalization, with contents of functional groups of 9.80 and 3.60% for GO-V and GO-A, respectively. The strong elastomer-graphene oxide interaction accelerates the crosslinking reaction and causes an important enhancement of the mechanical properties and thermal stability of composites. In addition, the swelling resistance to acid, base, and organic solvents is improved by more than 30%. These functional properties make FSE/GO composites a promising new class of advanced materials, expanding their potential application in edge technologies, spanning the manufacture of automotive components, aerospace and aviation parts, oil, gas, and petrochemical components, among others, particularly, seals, gaskets, valves and pipelines, or different components exposed to oil or solvent and high temperatures that require higher performance compared to conventional FSE products.
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