材料科学
反射损耗
微波食品加热
电介质
介电损耗
极化(电化学)
微观结构
复合材料
纳米颗粒
光电子学
纳米技术
复合数
化学
物理
物理化学
量子力学
作者
Jiahang Qiu,Yan Liu,Yang Xiang,Mu Zhang,Rongzhi Zhao,Xiaodong Li,Song Ma,Zhengtang Luo,Xuefeng Zhang,Xudong Sun
出处
期刊:Small
[Wiley]
日期:2023-11-10
标识
DOI:10.1002/smll.202308270
摘要
Abstract It is an urgent problem to realize reliable microwave absorption materials (MAMs) with low density. To address this issue, a series of controlled experiments w ere carried out, which indicated that the tubular structure enables excellent microwave absorption properties with a lower powder filling rate. This performance is attributable to the combined dielectric and magnetic loss mechanisms provided by Co/C and the interface polarization facilitated by multiple heterogeneous interfaces. Particularly, Co@C nanotubes, benefiting from the enhanced heterointerface polarization due to their abundant specific surface area and the reduced electron migration barrier induced by their 1D stacked structure, effectively achieved a dual enhancement of dielectric loss and polarization loss at lower powder filling ratios. Furthermore, the magnetic coupling effect of magnetic nanoparticle arrays in tubular structures is demonstrated by micromagnetic simulation, which have been few reported elsewhere. These propertied enable Co@C nanotubes to achieve minimum reflection loss and maximum effective absorption broadband values of 61.0 dB and 5.5 GHz, respectively, with a powder filling ratio of 20 wt% and a thickness of 1.94 mm. This study reveals the significance of designing 1D structures in reducing powder filling ratio and matching thickness, providing valuable insights for developing MAMs with different microstructures.
科研通智能强力驱动
Strongly Powered by AbleSci AI