Cationic Defect Engineering in Perovskite La2CoMnO6 for Enhanced Electrocatalytic Oxygen Evolution

The urgent need to promote the development of sustainable energy conversion requires exploration of highly efficient oxygen evolution reaction (OER) electrocatalysts. Defect engineering is a promising approach to address the inherent low electrical conductivity of metal oxides and limited reaction sites, for use in clean air applications and as electrochemical energy-storage electrocatalysts. In this article, oxygen defects are introduced into La₂CoMnO_6-δ perovskite oxides through the A-site cation defect strategy. By tuning the content of the A-site cation, oxygen defect concentration and corresponding electrochemical OER performance have been greatly improved. As a result, the defective La_1.8CoMnO_6-δ (L_1.8CMO) catalyst exhibits exceptional OER activity with an overpotential of 350 mV at 10 mA cm^-2, approximately 120 mV lower than that of the pristine perovskite. This enhancement can be attributed to the increase in surface oxygen vacancies, optimized e_g occupation of transition metal at the B-site, and enlarged Brunauer-Emmett-Teller surface area. The reported strategy facilitates the development of novel defect-mediated perovskites in electrocatalysis.