Interface Engineering of Inverted Perovskite Solar Cells Using a Self‐doped Perylene Diimide Ionene Terpolymer as a Thickness‐Independent Cathode Interlayer†

Comprehensive Summary Inverted perovskite solar cells (PerSCs) are a highly promising candidate in the photovoltaic field due to their low‐temperature fabrication process, negligible hysteresis, and easy integration with Si‐based solar cells. A cathode interlayer (CIL) is necessary in the development of inverted devices to reduce the trap density and energy barrier between the electron transport layer (ETL) and the electrode. However, most CILs are highly thickness‐sensitive due to low conductivity and poor film‐forming. In this study, we report on a self‐doping perylene imide‐based ionene polymer (PNPDIN) used as CIL material to modify electrode in inverted PerSCs. PNPDIN exhibits high conductivity and a good solubility in polar solvent, which results in an improved power conversion efficiency (PCE) from 10.05% (device without a CIL) to 16.97%. When the blend of PNPDIN and Bphen was used as a mixed CIL, the PCE of PerSCs can be further increased to 21.28% owing to the excellent morphology and matched energy level. More importantly, the PCE of the device is highly tolerant to the thickness of the mixed CIL, which benefited from the high conductivity of PNPDIN. This development is expected to provide an excellent mixed CIL material for roll‐to‐roll processing efficient and stable inverted PerSCs.