阻燃剂
法拉第效率
阳极
锂(药物)
材料科学
电解质
无机化学
金属
电池(电)
化学工程
磷酸铁锂
磷酸三甲酯
金属锂
电化学
磷酸盐
工程类
冶金
化学
有机化学
医学
电极
功率(物理)
物理化学
内分泌学
物理
量子力学
作者
Shuru Chen,Jianming Zheng,Yu Lu,Xiaodi Ren,Mark H. Engelhard,Chaojiang Niu,Hongkyung Lee,Wu Xu,Jie Xiao,Jun Li,Ji‐Guang Zhang
出处
期刊:Joule
[Elsevier]
日期:2018-08-01
卷期号:2 (8): 1548-1558
被引量:435
标识
DOI:10.1016/j.joule.2018.05.002
摘要
Rechargeable lithium metal batteries are regarded as the “holy grail” of energy storage systems, but their practical applications have long been hindered by poor cyclability and severe safety concerns. In this work, we report a fire-retardant localized high-concentration electrolyte consisting of 1.2 M lithium bis(fluorosulfonyl)imide in a mixture of flame-retardant triethyl phosphate/bis(2,2,2-trifluoroethyl) ether (1:3 by mol) for 4-V class lithium metal batteries. This electrolyte enables stable, dendrite-free cycling of lithium metal anodes with high Coulombic efficiency of up to 99.2%. Moreover, it exhibits excellent anodic stability even up to 5.0 V and greatly enhances the cycling performance of lithium metal batteries. A Li||LiNi0.6Mn0.2Co0.2O2 battery using this electrolyte can retain >97% capacity after 600 cycles at 1 C rate (ca. 1.6 mA cm−2), corresponding to a negligible capacity decay of <0.005% per cycle. Therefore, this new electrolyte can enable safe operation of high-energy lithium metal batteries for practical applications.
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