Electrochemical Kinetic Analysis of Carbon Steel Powders Produced by High-Energy Ball Milling

This work reports on the electrochemical kinetic analysis of carbon steel powders produced during the milling of carbon steel chips for 2, 3, and 5 h under an air atmosphere in a high-energy ball miller. This work aims to fill the gap in the literature regarding the transformation processes that affect carbon steel powder production. This information can be crucial for specific powder metallurgy systems. The results obtained using the Rietveld refinement method showed a decrease in the crystallite size, an increase in the microstrain, and no changes in the lattice parameter with the milling process. The electrochemical results revealed a strong influence of anodic electroactivity with milling time in NaCl solution, in contrast with NaOH, where the influence of the milling process was not significant. These results clearly show the significant role of chloride ions in preventing the formation of a passive film in milling with NaCl solution and in contrast to the formation of a passive film that notoriously inhibits both the anodic and cathodic reactions in milling with NaOH solution. The novelty of this work lies in the experimental demonstration of milling’s influence on the surface properties of carbon steel powders that directly affect their electrochemical response.