超级电容器
材料科学
电极
纳米片
电容
MXenes公司
电化学
碳化钛
纳米技术
功率密度
热液循环
硫化物
化学工程
钛
化学
冶金
功率(物理)
物理
物理化学
量子力学
工程类
作者
Jiqiu Qi,Huwei Gu,Chenya Ruan,Lei Zhu,Qingkun Meng,Yanwei Sui,Xiujuan Feng,Wenqing Wei,Hao Zhang
出处
期刊:Ionics
[Springer Nature]
日期:2022-04-11
卷期号:28 (6): 2979-2989
被引量:17
标识
DOI:10.1007/s11581-022-04516-4
摘要
MXene, an emerging 2D material, has aroused great concern in the field of supercapacitors owing to its charming properties. However, the relatively low specific capacitance of pristine MXene is unsatisfactory, which is caused by the restacking issue of MXene nanosheets. In this paper, a facile and cost-effective electrostatic self-assembly followed by hydrothermal method was adopted to prepare NiCo2S4 decorated multilayer MXene nanosheets (MXene/NiCo2S4). The introduced NiCo2S4 effectively alleviates the self-restacking of MXene nanosheet and facilitates ion accessibility. Hence, the as-prepared MXene/NiCo2S4 electrode displays a maximum specific capacitance of 1211.1 F g−1 at 1 A g−1, surpassing the NiCo2S4 electrode (938.4 F g−1 at 1 A g−1) and pure MXene electrode (84.2 F g−1 at 1 A g−1). The assembled asymmetrical supercapacitor utilizing hybrid MXene/NiCo2S4 and RGO delivers a high energy density of 38.7 Wh kg−1 and high power density of 6137 W kg−1. This work can provide a reliable reference for the synthesis of hybrid MXene/sulfide electrodes with ideal electrochemical performance.
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