Abstract Chemical Thermodynamics discusses the fundamental laws of thermodynamics along with their relationships to heat, work, enthalpy, entropy, and temperature. Predicting the direction of a spontaneous change and calculating the change in entropy of a reaction are core concepts. The relationship between entropy, free energy and work is covered. The Gibbs free energy is used quantitatively to predict if reactions or processes are going to be exothermic and spontaneous or endothermic under the stated conditions. Also explored are the enthalpy and entropy changes during a phase change. Finally the Gibbs free energy of a chemical reaction is related to its equilibrium constant and the temperature.